Let $L/K$ be a field extension. Suppose $f(x)$ is the minimal polynomial of $\alpha$ and $\alpha'$ over $K$ and suppose $g(x)$ is the minimal polynomial of $\beta$ and $\beta'$ over $K$. If $L = (\alpha, \beta)$, is it true that the rules $\sigma(\alpha) = \alpha'$ and $\sigma(\beta) = \beta'$ define a $K$-automorphism of $L$?
For example: $\mathbb{Q} \subset \mathbb{Q}(\sqrt{7}, \sqrt{13})$. I wish to define an automorphism $\sigma$ satisfying $\sigma(\sqrt{7}) = - \sqrt{7}$ and $\sigma(\sqrt{13}) = \sqrt{13}$. That is, I put $\sigma(a + b \sqrt{7} + c\sqrt{13} + d \sqrt{91}) = a - b \sqrt{7} + c \sqrt{13} - d \sqrt{91}$. Will this always extend to a ring morphism?
If this is not true, then how do I define an automorphism in practice? Do I always have to check that $\sigma$ is multiplicative?